Tungsten alloy is a kind of tungsten based (tungsten content of 85%
~99%), and add a small amount of Ni.Cu, Fe. Co. Mo, Cr and other
elements of the alloy, its density is up to 16.5~ 18.75g/cm3, known
as high specific gravity alloy, heavy alloy or high density
tungsten alloy.Tungsten alloy is widely used in electronics and
electric light source industry, and is also used in aerospace,
casting, weapons and other sectors to make rocket nozzle, die
casting mold, armor piercing core, contacts, heating body and heat
shield. Molybdenum tungsten alloyAn alloy containing two
elements, molybdenum and tungsten, including molybdenum based
molybdenum tungsten alloy and tungsten based tungsten molybdenum
alloy series. The alloy can be formed in any proportion and is
a complete solid solution alloy at all temperatures.Niobium
tungsten alloyA niobium alloy based on niobium formed by adding a
certain amount of tungsten and other elements. Tungsten and
niobium form infinite solid solutions. Tungsten is an
effective strengthening element of niobium, but with the increase
of tungsten addition, the plasticity and brittleness transition
temperature of the alloy will rise, and the grain will grow
significantly. Therefore, in order to obtain high strength
niobium tungsten alloy, it is necessary to properly control the
addition of tungsten, and at the same time, it is necessary to add
appropriate amount of elements such as zirconium and hafnium to
refine the grain and reduce the plastic-brittle transition
temperature. In 1961, the United States successfully developed
Nb-10W-2.5Zr alloy for the skin of the space shuttle, and later
developed into Nb-10W-1Zr-0.1C alloy. In the early 1970s,
China also successfully developed NbWl0Zr2.5 and NbWl0Zr1C0.1
alloys.Hard metal alloyHard alloy is the most common and main form
of tungsten alloy. Unlike the previous tungsten alloys, it is
tungsten, carbon and cobalt, so it is often called tungsten-cobalt
alloy. The most widely used tools in the industrial field are
basically carbide tools, so carbide this tungsten alloy is also
known as "industrial teeth".Development history editorIn 1907, a
tungsten alloy with low nickel content was introduced. It was
prepared by mechanical processing, but severe brittleness prevented
its application. It was not until 1909 that W. D. Coolidge of
General Electric Company in the United States made tungsten billet
by powder metallurgy and then mechanically processed it to produce
tungsten wire with ducibility at room temperature, thus laying the
foundation of tungsten wire processing industry as well as powder
metallurgy.However, this "ductile" tungsten alloy shows significant
brittleness after the light bulb is lit. In 1913, Pintsch
invented thorium tungsten filament (ThO2 content of 1% to 2%),
which greatly reduced the brittleness of the incandescent
filament. At first, the droop of the filament was not a
problem, because the filament was straight at that time. However,
after 1913, Langmuir changed the straight filament into spiral
filament. In this way, when the bulb was used, the high working
temperature and dead weight made the filament droop, so it was
difficult for both pure tungsten and thorium tungsten to meet the
application requirements.In order to solve the problems of sagging
tungsten wire and short life, in 1917, A. SPZ invented tungsten
alloy with "no deformation" at high temperature. At first, he
used a refractory crucible to roast WO3 when preparing pure
tungsten. He accidentally found that the tungsten wire spiral made
from the tungsten powder reduced by such WO3 mysteriously did not
sag after recrystallization. Subsequently, after 218 times of
repeated experimental verification, he finally found that in
tungstic acid (WO3·H2O) adding potassium and sodium silicate, after
reduction, pressing, sintering, processing and so on to make
tungsten wire, recrystallization to form a very coarse grain
structure, neither soft and anti sagging, this is the earliest
non-sagging tungsten wire. Beth's discovery laid the
foundation for the production of undrooped tungsten wire, which is
still called "218 tungsten wire" in the United States, in honor of
Beth's discovery.The production process of doped tungsten alloy is
lengthy, including tungsten smelting, powder metallurgy and plastic
processing.Ammonium paratungstate (APT) is usually used as raw
material in the production of doped tungsten alloys. In
addition to the traditional classical process, the extraction
method and ion exchange method were studied internationally in the
1950s, and these processes were also adopted in China in the 1970s,
thus simplifying the process flow and improving the recovery rate
of tungsten. Since the 1960s, many countries have adopted blue
tungsten oxide doping process to replace tungsten trioxide doping,
so as to improve the doping effect. Pickling of tungsten
powder began to be applied to production in the 1960s, its main
purpose is to wash away the excess dopant, ultrafine powde
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